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0001 0002 0003 Notes: hydrazine and NASA 0004 0005 0006 ============================================================ 0007 FN ISI Export Format 0008 VR 1.0 0009 PT S 0010 AU Qian, T 0011 Xu, R 0012 Kwan, C 0013 Linnell, B 0014 Young, R 0015 TI Toxic vapor classification and concentration estimation for Space 0016 Shuttle and International Space Station 0017 SO ADVANCES IN NEURAL NETWORKS - ISNN 2004, PT 1 0018 SE LECTURE NOTES IN COMPUTER SCIENCE 0019 LA English 0020 DT Article 0021 ID SUPPORT VECTOR MACHINES 0022 AB During space walks, the space suits of astronauts may be contaminated 0023 by toxic vapors such as hydrazine, which are used for attitude control. 0024 Here we present some initial results on vapor classification and 0025 concentration estimation by using Support Vector Machine. (SVM). The 0026 vapor was collected by electronic nose. By collaborating closely with 0027 NASA KCS, we achieved great results. For example, for Kam15f 0028 (90-second) data set, the classification success rate was 97.5% using 0029 SVM as compared to 87% using the linear discriminant method in [1]. 0030 Comparative studies were conducted between the SVM classifier and other 0031 classifiers such as Back Propagation (BP) Neural Network, Probability 0032 Neural Network (PNN), and, Learning Vector Quantization (LVQ). In all 0033 cases, the SVM classifier showed superior performance over other 0034 classifiers. In the concentration estimation part by using SVM, we 0035 achieved more than 99% correct estimation of concentration by using the 0036 90(th) second data samples. 0037 C1 Intelligent Automat Inc, Rockville, MD 20855 USA. 0038 NASA, Kennedy Space Ctr, FL 32899 USA. 0039 RP Qian, T, Intelligent Automat Inc, 15400 Calhoun Dr,Suite 400, 0040 Rockville, MD 20855 USA. 0041 EM tqian@i-a-i.com 0042 hgxu@i-a-i.com 0043 ckwan@i-a-i.com 0044 Bruce.Linnell-1@ksc.nasa.gov 0045 Rebecca.C.Young@nasa.gov 0046 NR 6 0047 TC 0 0048 PU SPRINGER-VERLAG BERLIN 0049 PI BERLIN 0050 PA HEIDELBERGER PLATZ 3, D-14197 BERLIN, GERMANY 0051 SN 0302-9743 0052 J9 LECT NOTE COMPUT SCI 0053 PY 2004 0054 VL 3173 0055 BP 543 0056 EP 551 0057 PG 9 0058 SC Computer Science, Theory & Methods 0059 GA BAT64 0060 UT ISI:000223492600090 0061 ER 0062 0063 0064 PT J 0065 AU Zelnick, SD 0066 Mattie, DR 0067 Stepaniak, PC 0068 TI Occupational exposure to hydrazines: Treatment of acute central nervous 0069 system toxicity 0070 SO AVIATION SPACE AND ENVIRONMENTAL MEDICINE 0071 LA English 0072 DT Review 0073 DE aviation; hydrazine; treatment 0074 ID UREA CYCLE DISORDERS; ISONIAZID OVERDOSE; UDMH INTOXICATION; 0075 PYRIDOXINE; MANAGEMENT; THERAPY; INHIBITION; ENZYMES; INVIVO; RAT 0076 AB ZELNICK SD, MATTIE DR, STEPANIAK PC. Occupational exposure to 0077 hydrazines: treatment of acute central nervous system toxicity. Aviat 0078 Space Environ Med 2003; 74:1285-91. 0079 Exposure to hydrazine and hydrazines' alkylated derivatives is an 0080 important occupational health issue, which will increase in 0081 significance as space applications increase. Despite their widespread 0082 usage as rocket fuels in manned and unmanned space and missile systems, 0083 serious exposures to hydrazines are rare. While a significant number of 0084 experimental studies were performed in the late 1950s through the 0085 mid-1960s, conflicting information exists concerning the most 0086 appropriate treatment for these exposures. A cross-sectional study 0087 evaluating the most common rocket fuels such as hydrazine; 0088 1,1-dimethylhydrazine (UDMH); mono-methylhydrazine (MMH); and 0089 Aerozine-50 against the most commonly suggested therapies, such as 0090 pyridoxine, traditional antiseizure therapies, and arginine is needed 0091 to clarify the treatment implications for human exposure. Treatments 0092 that have been useful for hyperammonemic states, such as those for the 0093 six inherited urea cycle defects, have significant potential for the 0094 improvement of hydrazine exposure treatment. 0095 C1 US Dept Def, Manned Space Flight Off, Div Med, Patrick AFB, FL USA. 0096 USAF, Res Lab, Wright Patterson AFB, OH 45433 USA. 0097 NASA, Contingency Med Operat Grp, Space Med & Crew Hlth Syst, Houston, TX USA. 0098 RP Zelnick, SD, US Dept Def, Manned Space Flight Off, Div Med, 1201 Edward 0099 H White II St,MS 7101,Bldg 423,Room S, Patrick AFB, FL USA. 0100 NR 47 0101 TC 3 0102 PU AEROSPACE MEDICAL ASSOC 0103 PI ALEXANDRIA 0104 PA 320 S HENRY ST, ALEXANDRIA, VA 22314-3579 USA 0105 SN 0095-6562 0106 J9 AVIAT SPACE ENVIRON MED 0107 JI Aviat. Space Environ. Med. 0108 PD DEC 0109 PY 2003 0110 VL 74 0111 IS 12 0112 BP 1285 0113 EP 1291 0114 PG 7 0115 SC Public, Environmental & Occupational Health; Medicine, General & 0116 Internal; Sport Sciences 0117 GA 751XH 0118 UT ISI:000187115000012 0119 ER 0120 0121 0122 PT J 0123 AU Barragan, M 0124 Woods, S 0125 Julien, HL 0126 Wilson, DB 0127 Saulsberry, R 0128 TI Thermodynamic equations of state for hydrazine and monomethylhydrazine 0129 SO COMBUSTION AND FLAME 0130 LA English 0131 DT Article 0132 AB Thermodynamic equations of state are evaluated for the aerospace fuels 0133 hydrazine and monomethylhydrazine using Peng-Robinson (PR) and 0134 Soave-Redlich-Kwong (SRK) formulations. The PR formulation is shown to 0135 be the best fit for hydrazine, and the SRK formulation to be the best 0136 fit for monomethylhydrazine, based on available critical property data 0137 and evaluations of thermodynamic consistency. The adequacy of the 0138 differing property data for these fuels in the literature is discussed, 0139 and the methodology used to validate the formulations is outlined. The 0140 importance of using appropriate real fluid equations of state in 0141 thermodynamic safety and hazards analysis of fuel systems is 0142 demonstrated by considering an adiabatic compression of gaseous fuels 0143 previously postulated in accident scenarios of aerospace propulsion 0144 systems. Calculation of isentropic compression temperatures for pure 0145 components using ideal gas constant heat capacity, ideal gas with 0146 variable heat capacity, and real fluid equations of state are compared 0147 to illustrate the need for real fluid equations of state. In addition, 0148 three separate approaches are used for estimating isentropic 0149 compression temperatures for mixtures involving these fuels, again 0150 illustrating the importance of treating these mixtures as real fluids 0151 for design and safety analysis. (C) 2002 by The Combustion Institute. 0152 C1 NASA, Honeywell Technol Solut Inc, White Sands Test Facil, Las Cruces, NM USA. 0153 NASA, Lyndon B Johnson Space Ctr, White Sands Test Facil, Las Cruces, NM USA. 0154 RP Julien, HL, NASA, Honeywell Technol Solut Inc, White Sands Test Facil, 0155 Las Cruces, NM USA. 0156 NR 20 0157 TC 1 0158 PU ELSEVIER SCIENCE INC 0159 PI NEW YORK 0160 PA 360 PARK AVE SOUTH, NEW YORK, NY 10010-1710 USA 0161 SN 0010-2180 0162 J9 COMBUST FLAME 0163 JI Combust. Flame 0164 PD NOV 0165 PY 2002 0166 VL 131 0167 IS 3 0168 BP 316 0169 EP 328 0170 PG 13 0171 SC Thermodynamics; Energy & Fuels; Engineering, Multidisciplinary; 0172 Engineering, Chemical 0173 GA 618MD 0174 UT ISI:000179421100008 0175 ER 0176 0177 0178 PT J 0179 AU Doerr, DF 0180 TI Development of an advanced rocket propellant Handler's suit 0181 SO ACTA ASTRONAUTICA 0182 LA English 0183 DT Article 0184 AB Most launch vehicles and satellites in the US inventory rely upon the 0185 use of hypergolic rocket propollants, many of which are toxic to 0186 humans. These fuels and oxidizers, such as hydrazine and nitrogen 0187 tetroxide have threshold limit values as low as 0.01 PPM. It is 0188 essential to provide space workers handling these agents whole body 0189 protection as they are universally hazardous not only to the 0190 respiratory system, but the skin as well. This paper describes a new 0191 method for powering a whole body protective garment to assure the 0192 safety of ground servicing crews. 0193 A new technology has been developed through the small business 0194 innovative research program at the Kennedy Space Center. Currently, 0195 liquid air is used in the environmental control unit (ECU) that powers 0196 the propellant handlers suit (PHE). However, liquid air exhibits 0197 problems with attitude dependence, oxygen enrichment, and difficulty 0198 with reliable quantity measurement. The new technology employs the 0199 storage of the supply air as a supercritical gas. This method of air 0200 storage overcomes ail of three problems above while maintaining high 0201 density storage at relatively low vessel pressures (< 7000 kPa or 0202 similar to 1000 psi). A one hour prototype ECU was developed and tested 0203 to prove the feasibility of this concept. This was upgraded by the 0204 design of a larger supercritical dewar capable of holding 7 Kg of air, 0205 a supply which provides a 2 hour duration to the PHE. A third version 0206 is being developed to test the feasibility of replacing existing air 0207 cooling methodology with a liquid cooled garment for relief of heat 0208 stress in this warm Florida environment. 0209 Testing of the first one hour prototype yielded data comprobable to the 0210 liquid air powered predecessor, but enjoyed advantages of attitude 0211 independence and oxygen level stability. Thermal data revealed heat 0212 stress relief at least as good as liquid air supplied units. 0213 The application of supercritical air technology to this whole body 0214 protective ensemble marked an advancement in the state-of-the-art in 0215 personal protective equipment. Not only was long duration environmental 0216 control provided, but it was done without a high pressure vessel. The 0217 unit met human performance needs for attitude independence, oxygen 0218 stability, and relief of heat stress. This supercritical air (and 0219 oxygen) technology is suggested for microgravity applications in life 0220 support such as the Extravehicular Mobility Unit. (C) 2001 Published by 0221 Elsevier Science Ltd. 0222 C1 NASA, Kennedy Space Ctr, FL 32899 USA. 0223 RP Doerr, DF, NASA, Kennedy Space Ctr, FL 32899 USA. 0224 NR 0 0225 TC 1 0226 PU PERGAMON-ELSEVIER SCIENCE LTD 0227 PI OXFORD 0228 PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND 0229 SN 0094-5765 0230 J9 ACTA ASTRONAUT 0231 JI Acta Astronaut. 0232 PD AUG-NOV 0233 PY 2001 0234 VL 49 0235 IS 3-10 0236 BP 463 0237 EP 468 0238 PG 6 0239 SC Engineering, Aerospace 0240 GA 468HK 0241 UT ISI:000170751900035 0242 ER 0243 0244 0245 PT J 0246 AU Cardelino, BH 0247 Moore, CE 0248 Cardelino, CA 0249 Frazier, DO 0250 Bachmann, KJ 0251 TI Theoretical study of indium compounds of interest for organometallic 0252 chemical vapor deposition 0253 SO JOURNAL OF PHYSICAL CHEMISTRY A 0254 LA English 0255 DT Article 0256 ID MOLECULAR-ORBITAL THEORY; EXTENDED BASIS-SETS; POTENTIAL-ENERGY 0257 SURFACES; DENSITY-FUNCTIONAL THEORY; IR MATRIX-ISOLATION; SPECTROSCOPIC 0258 CONSTANTS; ELECTRONIC STATES; PSEUDOPOTENTIAL APPROXIMATION; 0259 DISSOCIATION-ENERGIES; TRANSITION-METALS 0260 AB The structural, electronic, and thermochemical properties of indium 0261 compounds which are of interest in halide transport and organometallic 0262 chemical vapor deposition processes have been studied by ab initio and 0263 statistical thermodynamic methods. The compounds reported include: 0264 indium halides and hydrides (InF, InCl, InCl3, InH, InH2, InH3); indium 0265 clusters (In-2, In-3); methylindium, dimethylindium, and their hydrogen 0266 derivatives [In(CH3), In(CH3)H, In(CH3)H-2, In(CH3)(2), In(CH3)(2)H]; 0267 dimethylindium dimer [In-2(CH3)(4)] and trimethylindium [In(CH3)(3)]; 0268 dehydrogenated methyl-, dimethyl-, and trimethylindium [In(CH3)(2)CH2, 0269 In(CH3)CH2. In(CH2)]; trimethylindium adducts with ammonia, 0270 trimethylamine and hydrazine [(CH3)(3)In:NH3, (CH3)(3)In:N(CH3)(3), 0271 (CH3)(3)In:N(H-2)N(H-2)]; dimethylamino-indium and methylimino-indium 0272 [In(CH3)(2)(NH2). In(CH3)(NH)]; indium nitride and indium nitride dimer 0273 (InN, In2N2); indium phosphide, -arsenide, and -antimonide (InP, InAs, 0274 InSb). The predicted electronic properties are based on density 0275 functional theory calculations; the calculated thermodynamic properties 0276 are reported following the format of the JANAF (Joint Army, Navy, NASA, 0277 Air Force) Tables. Equilibrium compositions at two temperatures (298 0278 and 1000K) have been analyzed for groups of competing simultaneous 0279 reactions. 0280 C1 Spelman Coll, Dept Chem, Atlanta, GA 30314 USA. 0281 NASA, George C Marshall Space Flight Ctr, Space Sci Lab, Huntsville, AL 35812 USA. 0282 Georgia Inst Technol, Sch Earth & Atmospher Sci, Atlanta, GA 30332 USA. 0283 N Carolina State Univ, Dept Mat Sci & Engn, Raleigh, NC 27695 USA. 0284 RP Cardelino, BH, Spelman Coll, Dept Chem, Box 238, Atlanta, GA 30314 USA. 0285 NR 88 0286 TC 7 0287 PU AMER CHEMICAL SOC 0288 PI WASHINGTON 0289 PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA 0290 SN 1089-5639 0291 J9 J PHYS CHEM A 0292 JI J. Phys. Chem. A 0293 PD FEB 8 0294 PY 2001 0295 VL 105 0296 IS 5 0297 BP 849 0298 EP 868 0299 PG 20 0300 SC Chemistry, Physical; Physics, Atomic, Molecular & Chemical 0301 GA 400AF 0302 UT ISI:000166845900008 0303 ER 0304 0305 0306 PT S 0307 AU Johnson, NL 0308 TI The cause and consequences of a satellite fragmentation: A case study 0309 SO SPACE DEBRIS 0310 SE ADVANCES IN SPACE RESEARCH 0311 LA English 0312 DT Article 0313 AB The fragmentation of a Pegasus Hydrazine Auxiliary Propulsion System 0314 upper stage on 3 June 1996 stands as the worst satellite breakup on 0315 record in terms of cataloged orbital debris. In addition to the more 0316 than 700 debris large enough to be tracked (approximately 10 cm in 0317 diameter or greater) in the 200 km by 2,000 km orbital regime by the 0318 U.S. Space Surveillance Network, a debris population of up to 300,000 0319 objects larger than 4 mm appears to have been generated, based upon 0320 special radar observations. The debris cloud presented an immediate 0321 threat to many resident space objects, such as the Hubble Space 0322 Telescope, which resided in an orbit just 25 kin below the breakup 0323 altitude. Special analyses were required to ensure the safety of the 0324 STS-82 Hubble Space Telescope servicing mission in February 1997. This 0325 paper describes the activities undertaken-at the National Aeronautics 0326 and Space Administration Lyndon B. Johnson Space Center to characterize 0327 the near-term and far-term hazard of the debris cloud to manned and 0328 robotic spacecraft and to investigate the probable cause of the 0329 accident. The role of composite materials in the vehicle may have led 0330 to the creation of a much larger number of debris than would have been 0331 expected from a more conventional upper stage. To avoid a repetition of 0332 the incident, the Hydrazine Auxiliary Propulsion System upper stage was 0333 modified before its next launch, and additional passivation measures 0334 were adopted. This fragmentation event represents a textbook case for 0335 the hazards posed by satellite breakups and how fragmentation potential 0336 can be reduced without significantly affecting the capability of the 0337 vehicle. Published by Elsevier Science Ltd on behalf of COSPAR. 0338 C1 NASA, Lyndon B Johnson Space Ctr, Orbital Debris Program Off, Houston, TX 77058 USA. 0339 RP Johnson, NL, NASA, Lyndon B Johnson Space Ctr, Orbital Debris Program 0340 Off, 2101 NASA Rd 1, Houston, TX 77058 USA. 0341 NR 0 0342 TC 3 0343 PU PERGAMON PRESS LTD 0344 PI OXFORD 0345 PA THE BOULEVARD LANGFORD LANE KIDLINGTON, OXFORD OX5 1GB, ENGLAND 0346 SN 0273-1177 0347 J9 ADV SPACE RES 0348 PY 1999 0349 VL 23 0350 IS 1 0351 BP 165 0352 EP 173 0353 PG 9 0354 SC Engineering, Aerospace; Astronomy & Astrophysics; Geosciences, 0355 Multidisciplinary; Meteorology & Atmospheric Sciences 0356 GA BM98C 0357 UT ISI:000080334700020 0358 ER 0359 0360 0361 PT J 0362 AU Lichon, PG 0363 Sankovic, JM 0364 TI Development and demonstration of a 600-second mission-average I-sp 0365 arcjet 0366 SO JOURNAL OF PROPULSION AND POWER 0367 LA English 0368 DT Article 0369 AB Recent advanced development has resulted in a 550-h demonstration of a 0370 hydrazine arcjet at a mission-average special impulse I,, of greater 0371 than 600 s, The laboratory-type arcjet thruster was operated at 1800 W 0372 through a flow rate schedule consistent with a flight application, The 0373 thruster demonstrated stable, high-efficiency operation for the 0374 duration of the test, The development effort leading to the 0375 demonstration addressed the operational and life issues associated with 0376 achieving high performance, As a result of the development activity, a 0377 wide range of performance Has also achieved, Performance levels of 0378 greater than 575 s at 1000 W and greater than 675 s at 2000 W were 0379 demonstrated. The problems encountered with extending low-power arcjet 0380 performance are discussed, Increased thruster component temperatures 0381 caused new life issues to be identified, along with low propellant flow 0382 rate stability limits, The elevated temperatures caused significant 0383 changes in the electrode geometry for a thruster based on the 0384 state-of-the-art tungsten anode designs, Three paths to solving the 0385 problem were attempted, including lowering the operating temperature 0386 through improved heat rejection, mechanical design changes to reduce 0387 thermal stresses, and higher strength materials selection, The success 0388 of this program provides substantial evidence that an arcjet capable of 0389 greater than 600-s mission-average specific impulse will be available 0390 in the near term for night qualification and application. 0391 C1 NASA,LEWIS RES CTR,CLEVELAND,OH 44135. 0392 RP Lichon, PG, OLIN AEROSP CO,REDMOND,WA 98073. 0393 NR 5 0394 TC 3 0395 PU AMER INST AERONAUT ASTRONAUT 0396 PI RESTON 0397 PA 1801 ALEXANDER BELL DRIVE, STE 500, RESTON, VA 22091 0398 SN 0748-4658 0399 J9 J PROPUL POWER 0400 JI J. Propul. Power 0401 PD NOV-DEC 0402 PY 1996 0403 VL 12 0404 IS 6 0405 BP 1018 0406 EP 1025 0407 PG 8 0408 SC Engineering, Aerospace 0409 GA VT426 0410 UT ISI:A1996VT42600004 0411 ER 0412 0413 0414 PT J 0415 AU PALASZEWSKI, B 0416 TI LUNAR MISSIONS USING ADVANCED CHEMICAL PROPULSION - SYSTEM-DESIGN ISSUES 0417 SO JOURNAL OF SPACECRAFT AND ROCKETS 0418 LA English 0419 DT Article 0420 AB To provide the transportation of lunar base elements to the Moon, large 0421 high-energy propulsion systems will be required. Advanced propulsion 0422 systems for lunar missions can provide significant launch mass 0423 reductions and payload increases. These mass reductions and added 0424 payload masses can be translated into significant launch cost savings 0425 for the lunar base missions. In this paper, the masses in low Earth 0426 orbit (LEO) were compared for several propulsion systems: nitrogen 0427 tetroxide/monomethyl hydrazine (NTO/MMH), oxygen/methane (O2/CH4), 0428 oxygen/hydrogen (O2/H-2), and metallized O2/H-2/Al propellants. Also, 0429 the payload mass increases enabled with O2/H-2 and O2/H-2/Al systems 0430 were addressed. In addition, many system design issues involving the 0431 engine thrust levels, engine commonality between the transfer vehicle 0432 and the excursion vehicle, and the number of launches to place the 0433 lunar mission vehicles into LEO will be discussed. Analyses of small 0434 lunar missions launched from a single STS-C night are also presented. 0435 RP PALASZEWSKI, B, NASA,LEWIS RES CTR,DIV SPACE PROPULS TECHNOL,LAUNCH 0436 VEHICLE PROPULS BRANCH,CLEVELAND,OH 44135. 0437 NR 22 0438 TC 6 0439 PU AMER INST AERONAUT ASTRONAUT 0440 PI RESTON 0441 PA 1801 ALEXANDER BELL DRIVE, STE 500, RESTON, VA 22091 0442 SN 0022-4650 0443 J9 J SPACECRAFT ROCKET 0444 JI J. Spacecr. Rockets 0445 PD MAY-JUN 0446 PY 1994 0447 VL 31 0448 IS 3 0449 BP 458 0450 EP 465 0451 PG 8 0452 SC Engineering, Aerospace 0453 GA NU611 0454 UT ISI:A1994NU61100016 0455 ER 0456 0457 0458 PT J 0459 AU SCHNEIDER, SJ 0460 TI LOW THRUST CHEMICAL ROCKET TECHNOLOGY 0461 SO SPACE TECHNOLOGY-INDUSTRIAL AND COMMERCIAL APPLICATIONS 0462 LA English 0463 DT Article 0464 AB An on-going technology program to improve the performance of low thrust 0465 chemical rockets for spacecraft on-board propulsion applications is 0466 reviewed. Improved performance and lifetime is sought by the 0467 development of new predictive tools to understand the combustion and 0468 flow physics, introduction of high temperature materials and improved 0469 component designs to optimize performance, and use of higher 0470 performance propellants. Improved predictive technology is sought 0471 through the comparison of both local and global predictions with 0472 experimental data. Predictions are based on both the RPLUS 0473 Navier-Stokes code with finite rate kinetics and the JANNAF 0474 methodology. Data were obtained with laser-based diagnostics along with 0475 global performance measurements. Results indicate that the modeling of 0476 the injector and the combustion process needs improvement in these 0477 codes and flow visualization with a technique such as two-dimensional 0478 laser-induced fluorescence (LIF) would aid in resolving issues of flow 0479 symmetry and shear layer combustion processes. High temperature 0480 material fabrication processes are under development and small rockets 0481 are being designed, fabricated, and tested using these new materials. 0482 Rhenium coated with iridium for oxidation protection was produced by 0483 the Chemical Vapor Deposition (CVD) process and enabled an 800 K 0484 increase in rocket operating temperature. Performance gains with this 0485 material in rockets using Earth storable propellants (nitrogen 0486 tetroxide and monomethylhydrazine or hydrazine) were obtained through 0487 component redesign to eliminate fuel film cooling and its associated 0488 combustion inefficiency while managing head end thermal soakback. 0489 Material interdiffusion and oxidation characteristics indicated that 0490 the requisite lifetimes of tens of hours were available for thruster 0491 applications. Rockets were designed, fabricated, and tested with 0492 thrusts of 22, 62, 440 and 550 N. Performance improvements of 10 to 20 0493 seconds specific impulse were demonstrated. Higher performance 0494 propellants were evaluated. These propellants, defined as space 0495 storable propellants, include liquid oxygen (LOX) as.the oxidizer with 0496 nitrogen hydrides or hydrocarbons as the fuels. Specifically, a 0497 LOX/hydrazine engine was designed, fabricated, and demonstrated to have 0498 a 95% theoretical c-star which translates into a projected vacuum 0499 specific impulse of 345 s at an area ratio of 204:1. Further 0500 performance improvement can be obtained by the use of LOX/hydrogen 0501 propellants, especially for manned spacecraft applications, and 0502 specific designs must be developed and advanced through flight 0503 qualification. 0504 RP SCHNEIDER, SJ, NASA,LEWIS RES CTR,CLEVELAND,OH 44135. 0505 NR 0 0506 TC 0 0507 PU PERGAMON-ELSEVIER SCIENCE LTD 0508 PI OXFORD 0509 PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD, ENGLAND OX5 1GB 0510 SN 0892-9270 0511 J9 SPACE TECHNOL 0512 JI Space Tech.-Ind. Comm. Appl. 0513 PD JAN 0514 PY 1994 0515 VL 14 0516 IS 1 0517 BP 31 0518 EP 44 0519 PG 14 0520 SC Engineering, Aerospace 0521 GA NQ809 0522 UT ISI:A1994NQ80900004 0523 ER 0524 0525 0526 PT J 0527 AU SOVEY, JS 0528 CURRAN, FM 0529 HAAG, TW 0530 PATTERSON, MJ 0531 PENCIL, EJ 0532 RAWLIN, VK 0533 SANKOVIC, JM 0534 TI DEVELOPMENT OF ARCJET AND ION PROPULSION FOR SPACECRAFT STATIONKEEPING 0535 SO ACTA ASTRONAUTICA 0536 LA English 0537 DT Article 0538 AB Near term flight applications of arcjet and ion thruster satellite 0539 station-keeping systems as well as development activities in Europe. 0540 Japan, and the United States are reviewed. At least two arcjet and 0541 three ion propulsion flights are scheduled during the 1992-1995 period. 0542 Ground demonstration technology programs are focusing on the 0543 development of kW-class hydrazine and ammonia arcjets and xenon ion 0544 thrusters. Recent work at NASA Lewis Research Center on electric 0545 thruster and system integration technologies relating to satellite 0546 stationkeeping and repositioning will also be summarized. 0547 RP SOVEY, JS, NASA,LEWIS RES CTR,CLEVELAND,OH 44135. 0548 NR 0 0549 TC 0 0550 PU PERGAMON-ELSEVIER SCIENCE LTD 0551 PI OXFORD 0552 PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD, ENGLAND OX5 1GB 0553 SN 0094-5765 0554 J9 ACTA ASTRONAUT 0555 JI Acta Astronaut. 0556 PD JUL 0557 PY 1993 0558 VL 30 0559 BP 151 0560 EP 164 0561 PG 14 0562 SC Engineering, Aerospace 0563 GA LQ343 0564 UT ISI:A1993LQ34300015 0565 ER 0566 0567 0568 PT J 0569 AU ZUBE, DM 0570 MYERS, RM 0571 TI THERMAL NONEQUILIBRIUM IN A LOW-POWER ARCJET NOZZLE 0572 SO JOURNAL OF PROPULSION AND POWER 0573 LA English 0574 DT Article 0575 AB Emission spectroscopy measurements were made of the plasma flow inside 0576 the nozzle of a 1-kW-class arcjet thruster. The thruster propellant was 0577 a hydrogen-nitrogen mixture used to simulate fully decomposed 0578 hydrazine. Several 0.25-mm-diam holes were drilled into the 12-mm-long 0579 diverging section of the tungsten thruster nozzle to provide side-on 0580 optical access to the internal flow. Electron excitation for atomic 0581 species and molecular vibrational and rotational temperatures were 0582 determined for the expanding plasma using relative line ratio 0583 techniques. The atomic excitation temperature decreased from 18,000 K 0584 at a location 3-mm downstream of the constrictor to 9000 K at a 0585 location 9 mm from the constrictor, while the molecular vibrational and 0586 rotational temperatures decreased from 6500 to 3000 K and 8000 to 3000 0587 K, respectively, between the same locations. The electron density, 0588 measured using H(beta) line Stark broadening, decreased from 0589 almost-equal-to 10(21) m-3 to 2 x 10(20) m-3 during the expansion in 0590 the nozzle. The results show that the plasma is in a nonequilibrium 0591 state throughout most of the nozzle, with relaxation times close to or 0592 larger than the particle residence time. 0593 C1 SVERDRUP TECHNOL INC,NASA,LEWIS RES CTR GRP,CLEVELAND,OH 44135. 0594 RP ZUBE, DM, UNIV STUTTGART,INST RAUMFAHRTSYST,W-7000 STUTTGART 80,GERMANY. 0595 NR 31 0596 TC 14 0597 PU AMER INST AERONAUT ASTRONAUT 0598 PI RESTON 0599 PA 1801 ALEXANDER BELL DRIVE, STE 500, RESTON, VA 22091 0600 SN 0748-4658 0601 J9 J PROPUL POWER 0602 JI J. Propul. Power 0603 PD JUL-AUG 0604 PY 1993 0605 VL 9 0606 IS 4 0607 BP 545 0608 EP 552 0609 PG 8 0610 SC Engineering, Aerospace 0611 GA LN143 0612 UT ISI:A1993LN14300007 0613 ER 0614 0615 0616 PT J 0617 AU EICEMAN, GA 0618 SALAZAR, MR 0619 RODRIGUEZ, MR 0620 LIMERO, TF 0621 BECK, SW 0622 CROSS, JH 0623 YOUNG, R 0624 JAMES, JT 0625 TI ION MOBILITY SPECTROMETRY OF HYDRAZINE, MONOMETHYLHYDRAZINE, AND 0626 AMMONIA IN AIR WITH 5-NONANONE REAGENT GAS 0627 SO ANALYTICAL CHEMISTRY 0628 LA English 0629 DT Article 0630 ID PLASMA CHROMATOGRAPHY; H2O 0631 AB Hydrazine (HZ) and monomethylhydrazine (MMH) in air were monitored 0632 continuously using a hand-held ion mobility spectrometer equipped with 0633 membrane inlet, Ni-63 ion source, acetone reagent gas, and ambient 0634 temperature drift tube. Response characteristics included detection 0635 limit, 6 ppb; linear range, 10-600 ppb; saturated response, >2 ppm; and 0636 stable response after 15-30 min. Ammonia interfered in hydrazines 0637 detection through a product ion with the same drift time as that for 0638 MMH and HZ. Acetone reagent gas was replaced with 5-nonanone to alter 0639 drift times of product ions and separate ammonia from MMH and HZ. 0640 Patterns in mobility spectra, ion identifications from mass spectra, 0641 and fragmentation cross-sections from collisional-induced dissociations 0642 suggest that drift times are governed by ion-cluster equilibria in the 0643 drift region of the mobility spectrometer. Practical aspects including 0644 calibration, stability, and reproducibility are reported from the use 0645 of a hand-held mobility spectrometer on the space shuttle Atlantis 0646 during mission STS-37. 0647 C1 KRUG LIFE SCI INC,HOUSTON,TX 77058. 0648 NASA,TOX VAPOR DETECT LAB,KENNEDY SPACE CTR,FL 32899. 0649 NASA,LYNDON B JOHNSON SPACE CTR,BIOMED OPERAT & RES BRANCH,HOUSTON,TX 77058. 0650 RP EICEMAN, GA, NEW MEXICO STATE UNIV,DEPT CHEM,LAS CRUCES,NM 88003. 0651 NR 22 0652 TC 18 0653 PU AMER CHEMICAL SOC 0654 PI WASHINGTON 0655 PA 1155 16TH ST, NW, WASHINGTON, DC 20036 0656 SN 0003-2700 0657 J9 ANAL CHEM 0658 JI Anal. Chem. 0659 PD JUL 1 0660 PY 1993 0661 VL 65 0662 IS 13 0663 BP 1696 0664 EP 1702 0665 PG 7 0666 SC Chemistry, Analytical 0667 GA LJ380 0668 UT ISI:A1993LJ38000013 0669 ER 0670 0671 0672 PT J 0673 AU PALASZEWSKI, B 0674 TI METALLIZED PROPELLANTS FOR THE HUMAN EXPLORATION OF MARS 0675 SO JOURNAL OF PROPULSION AND POWER 0676 LA English 0677 DT Article 0678 AB Advanced chemical propulsion using metallized propellants can enable 0679 significant launch mass reductions for piloted Mars missions. 0680 Metallized propellants allow the density and/or the specific impulse 0681 (I(sp)) of the propulsion system to increase. These density and I(sp) 0682 increases can reduce the propellant mass and the propulsion system dry 0683 mass. Both of these effects are discussed and analyzed in the paper. 0684 Detailed mass scaling equations and estimates of the I(sp) for the 0685 metallized propellant combinations are presented. The most significant 0686 savings with metallized propellants are derived from increasing the 0687 payload delivered to Mars. For the same mass in low Earth orbit (LEO), 0688 a metallized Mars vehicle can deliver 20-22% additional payload to the 0689 surface. Using metallized propulsion can accelerate the delivery and 0690 construction of a Mars base or outpost. This 20% payload increase 0691 reduces the total number of Mars flights and, therefore, significantly 0692 reduces the number of space transportation system-cargo (STS-C) 0693 launches for the entire Mars architecture. Using metallized propellants 0694 to reduce the mass in LEO per flight is not as effective as increasing 0695 the payload delivery capacity. While over 20% more payload can be 0696 delivered to Mars per mission, the mass savings per flight (while 0697 delivering the same payload with a higher I(sp) system) is much 0698 smaller. Using metallized propellants in all of the Mars propulsion 0699 systems, a modest 3.3% LEO mass savings is possible. This translates 0700 into a savings of 38,000 kg over that required with O2/H2 propulsion. 0701 The Mars excursion vehicle (MEV) using Earth- or space-storable 0702 propellants for the ascent can be an alternative to storing cryogenic 0703 H-2 on Mars. There will be a mass penally for using these alternatives 0704 because of the lower I(sp) of these systems. A space-storable system 0705 using oxygen/monomethyl hydrazine/aluminum (O2/MMH/Al) delivered the 0706 lowest mass penalty over O2/H2. For the expedition case missions, the 0707 LEO mass penalty for using metallized O2/MMH/Al is only 3-5%. 0708 RP PALASZEWSKI, B, NASA,LEWIS RES CTR,DIV SPACE PROPULS TECHNOL,METALLIZED 0709 PROPELLANT PROGRAM,CLEVELAND,OH 44135. 0710 NR 22 0711 TC 6 0712 PU AMER INST AERONAUT ASTRONAUT 0713 PI RESTON 0714 PA 1801 ALEXANDER BELL DRIVE, STE 500, RESTON, VA 22091 0715 SN 0748-4658 0716 J9 J PROPUL POWER 0717 JI J. Propul. Power 0718 PD NOV-DEC 0719 PY 1992 0720 VL 8 0721 IS 6 0722 BP 1192 0723 EP 1199 0724 PG 8 0725 SC Engineering, Aerospace 0726 GA JY976 0727 UT ISI:A1992JY97600010 0728 ER 0729 0730 0731 PT J 0732 AU CURRAN, FM 0733 HAAG, TW 0734 TI EXTENDED LIFE AND PERFORMANCE-TEST OF A LOW-POWER ARCJET 0735 SO JOURNAL OF SPACECRAFT AND ROCKETS 0736 LA English 0737 DT Article 0738 AB An automated, cyclic life test was performed to demonstrate the 0739 reliability and endurance of a low-power dc arcjet thruster. Over 1000 0740 h and 500 on-off cycles were accumulated, which would represent the 0741 requirements for about 15 years of on-orbit lifetime. A 0742 hydrogen/nitrogen propellant mixture was used to simulate decomposed 0743 hydrazine propellant, and the power level was nominally 1.2 kW after 0744 the burn-in period. The arcjet operated in a very repeatable fashion 0745 from cycle to cycle. The steady-state voltage increased by 0746 approximately 6 V over the first 300 h, and then by only 3 V through 0747 the remainder of the test. Thrust measurements taken before, during, 0748 and after the test verified that the thruster performed in a consistent 0749 fashion throughout the test at a specific impulse of 450-460 s. 0750 Post-test component evaluation revealed limited erosion on both the 0751 anode and cathode. Other thruster components, including graphite seals, 0752 appeared undamaged. 0753 RP CURRAN, FM, NASA,LEWIS RES CTR,DIV SPACE PROPULS TECHNOL,MAIL STOP 0754 SPTO-1,CLEVELAND,OH 44135. 0755 NR 31 0756 TC 11 0757 PU AMER INST AERONAUT ASTRONAUT 0758 PI RESTON 0759 PA 1801 ALEXANDER BELL DRIVE, STE 500, RESTON, VA 22091 0760 SN 0022-4650 0761 J9 J SPACECRAFT ROCKET 0762 JI J. Spacecr. Rockets 0763 PD JUL-AUG 0764 PY 1992 0765 VL 29 0766 IS 4 0767 BP 444 0768 EP 452 0769 PG 9 0770 SC Engineering, Aerospace 0771 GA JK341 0772 UT ISI:A1992JK34100004 0773 ER 0774 0775 0776 PT J 0777 AU MEYER, D 0778 WEBER, K 0779 SCOTT, W 0780 TI ELECTRIC AUXILIARY POWER UNIT FOR SHUTTLE EVOLUTION 0781 SO JOURNAL OF PROPULSION AND POWER 0782 LA English 0783 DT Article 0784 AB The Space Shuttle Orbiter currently uses three hydrazine-fueled 0785 auxiliary power units (APUs) to provide hydraulic power for the vehicle 0786 aerodynamic surface controls, main engine thrust vector control, 0787 landing gear, steering, and brakes. Electric APUs have been proposed as 0788 possible replacements to the hydrazine APUs. Along with the potential 0789 advantages, this paper describes an electric APU configuration and 0790 addresses the technical issues and risks associated with the subsystem 0791 components. In addition, characteristics of an electric APU compared 0792 with the existing APU and the direction of future study with respect to 0793 the electric APU are suggested. 0794 C1 NASA,LYNDON B JOHNSON SPACE CTR,APU SUBSYST PROGRAM,HOUSTON,TX 77058. 0795 SUNDSTRAND AEROSP,DEPT 741F6,ROCKFORD,IL 61125. 0796 RP MEYER, D, SUNDSTRAND AEROSP,DEPT 710E6,4747 HARRISON AVE,ROCKFORD,IL 0797 61125. 0798 NR 3 0799 TC 0 0800 PU AMER INST AERONAUT ASTRONAUT 0801 PI RESTON 0802 PA 1801 ALEXANDER BELL DRIVE, STE 500, RESTON, VA 22091 0803 SN 0748-4658 0804 J9 J PROPUL POWER 0805 JI J. Propul. Power 0806 PD JAN-FEB 0807 PY 1992 0808 VL 8 0809 IS 1 0810 BP 233 0811 EP 239 0812 PG 7 0813 SC Engineering, Aerospace 0814 GA GZ467 0815 UT ISI:A1992GZ46700032 0816 ER 0817 0818 0819 PT J 0820 AU COYNE, L 0821 MARINER, R 0822 RICE, A 0823 TI AIR OXIDATION OF HYDRAZINE .1. REACTION-KINETICS ON NATURAL KAOLINITES, 0824 HALLOYSITES, AND MODEL SUBSTITUENT LAYERS WITH VARYING IRON AND 0825 TITANIUM-OXIDE AND O-CENTER CONTENTS 0826 SO LANGMUIR 0827 LA English 0828 DT Article 0829 ID ELECTRON-SPIN RESONANCE; DOPED SYNTHETIC KAOLINITE; PARAMAGNETIC 0830 RESONANCE; LUMINESCENCE; SPECTRA; SURFACE; SPECTROSCOPY; MOSSBAUER 0831 AB Air oxidation of hydrazine was studied by using a group of kaolinites, 0832 halloysites, and substituent oxides as models for the tetrahedral and 0833 octahedral sheets. The rate was found to be linear with oxygen. The 0834 stoichiometry showed that oxygen was the primary oxidant and that 0835 dinitrogen was the only important nitrogen-containing product. The 0836 rates on kaolinites were strongly inhibited by water. Those on 0837 three-dimensional silica and gibbsite appeared not to be. That on a 0838 supposedly layered silica formed from a natural kaolinite by acid 0839 leaching showed transitional behavior - slowed relative to that 0840 expected from a second-order reaction relative to that on the gibbsite 0841 and silica but faster than those on the kaolinites. The most striking 0842 result of the reaction was the marked increase in the rate of reaction 0843 of a constant amount of hydrazine as the amount of clay was increased. 0844 This increase was apparent (in spite of the water inhibition at high 0845 conversions) over a 2 order of magnitude variation of the clay weight. 0846 The weight dependence was taken to indicate that the role of the clay 0847 is very important, that the number of reactive centers is very small, 0848 or that they may be deactivated over the course of the reaction. In 0849 contrast to the strong dependence on overall amount of clay, the 0850 variation of amounts of putative oxidizing centers, such as structural 0851 Fe(III), admixed TiO2 or Fe2O3, or O- centers, did not result in 0852 alteration of the rate commensurate with the degree of variation of the 0853 entity in question. Surface iron does play some role, however, as 0854 samples that were pretreated with a reducing agent were less active as 0855 catalysts than the parent material. These results were taken to 0856 indicate either that the various centers interact to such a degree that 0857 they cannot be considered independently or that the reaction might 0858 proceed by way of surface complexation, rather than single electron 0859 transfers. 0860 C1 SAN JOSE STATE UNIV,DEPT CHEM,SAN JOSE,CA 95192. 0861 ENGLISH CHINA CLAYS INT,SANDERSVILLE,GA 31082. 0862 RP COYNE, L, NASA,AMES RES CTR,MAIL STOP 239-4,MOFFETT FIELD,CA 94035. 0863 NR 42 0864 TC 1 0865 PU AMER CHEMICAL SOC 0866 PI WASHINGTON 0867 PA 1155 16TH ST, NW, WASHINGTON, DC 20036 0868 SN 0743-7463 0869 J9 LANGMUIR 0870 JI Langmuir 0871 PD AUG 0872 PY 1991 0873 VL 7 0874 IS 8 0875 BP 1660 0876 EP 1674 0877 PG 15 0878 SC Chemistry, Physical 0879 GA GC040 0880 UT ISI:A1991GC04000019 0881 ER 0882 0883 0884 PT J 0885 AU COYNE, LM 0886 SUMMERS, DP 0887 TI SURFACE ACTIVATION OF AIR OXIDATION OF HYDRAZINE ON KAOLINITE .2. 0888 CONSIDERATION OF OXIDIZING REDUCING ENTITIES IN RELATIONSHIP TO OTHER 0889 COMPOSITIONAL, STRUCTURAL, AND ENERGETIC FACTORS 0890 SO LANGMUIR 0891 LA English 0892 DT Article 0893 ID CLAY-MINERALS; LUMINESCENCE; OXIDE; IRON; DEHYDRATION; RESONANCE; 0894 CATALYSTS; SPECTRA; CENTERS 0895 AB The rates (previously reported) for the air oxidation of hydrazine on 0896 kaolinite and substituent oxides of kaolinite showed a complex 0897 dependence on the relative amounts of several structural 0898 oxidizing/reducing entities within the reaction-promoting solids. The 0899 rates indicated an important role of the clay but no dominant role of 0900 any one of the oxidizing/reducing entities. In this paper we review (a) 0901 the reaction-promoting activity of these centers as studied in other 0902 systems, (b) various spectroscopic results showing interaction between 0903 these entities in clays and (c) reported spectroscopic studies ot the 0904 complexation between hydrazine and aluminosilicate surfaces as a whole, 0905 in an effort to propose a mechanism for the reaction. Whereas some 0906 uncertainties remain, the present synthesis concludes that a mechanism 0907 operating through single electron/hole transfers and hydrogen atom 0908 transfers by discrete centers is adequate to explain the observed rate 0909 behaviors including the observed second order dependence of the 0910 oxidation rate on catalyst amount. The effects of these operations on 0911 the catalyst can result in no alteration of, or complete or partial 0912 electronic relaxation of its contingent of trapped separated charge 0913 pairs. The degree to which surface complexation as a whole, 0914 intercalation, or luminescent processes may also be associated with the 0915 reaction cannot be adequately assessed with the information in hand. 0916 C1 SAN JOSE STATE UNIV,DEPT CHEM,SAN JOSE,CA 95192. 0917 RP COYNE, LM, NASA,AMES RES CTR,PLANETARY BIOL BRANCH,MAIL STOP 0918 239-4,MOFFETT FIELD,CA 94035. 0919 NR 51 0920 TC 2 0921 PU AMER CHEMICAL SOC 0922 PI WASHINGTON 0923 PA 1155 16TH ST, NW, WASHINGTON, DC 20036 0924 SN 0743-7463 0925 J9 LANGMUIR 0926 JI Langmuir 0927 PD AUG 0928 PY 1991 0929 VL 7 0930 IS 8 0931 BP 1675 0932 EP 1688 0933 PG 14 0934 SC Chemistry, Physical 0935 GA GC040 0936 UT ISI:A1991GC04000020 0937 ER 0938 0939 0940 PT J 0941 AU DAVIS, DD 0942 WEDLICH, RC 0943 MARTIN, NB 0944 TI TRANSITION-METAL CATALYSIS OF THE HETEROGENEOUS DECOMPOSITION OF 0945 HYDRAZINE - ADIABATIC KINETICS BY ACCELERATING RATE CALORIMETRY 0946 SO THERMOCHIMICA ACTA 0947 LA English 0948 DT Article 0949 ID AMMONIA-SYNTHESIS; SURFACE; ENERGY; ADSORPTION; MECHANISM; OXYGEN; 0950 FILMS; CO2 0951 AB The thermochemical kinetics of the transition-metal-catalyzed 0952 decomposition reaction of hydrazine have been studied using 0953 accelerating rate calorimetry. The reaction stoichiometry was 0954 determined by both product analysis and thermochemical balance. In the 0955 range 350-515 K when both liquid and vapor hydrazine are present, the 0956 decomposition proceeds according to: 0957 C1 NASA,LOCKHEED ENGN & SCI CO,WHITE SANDS TEST FACIL,LAS CRUCES,NM 88004. 0958 RP DAVIS, DD, NEW MEXICO STATE UNIV,DEPT CHEM,LAS CRUCES,NM 88003. 0959 NR 52 0960 TC 2 0961 PU ELSEVIER SCIENCE BV 0962 PI AMSTERDAM 0963 PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS 0964 SN 0040-6031 0965 J9 THERMOCHIM ACTA 0966 JI Thermochim. Acta 0967 PD MAR 15 0968 PY 1991 0969 VL 175 0970 IS 2 0971 BP 175 0972 EP 188 0973 PG 14 0974 SC Chemistry, Analytical; Chemistry, Physical 0975 GA FE279 0976 UT ISI:A1991FE27900006 0977 ER 0978 0979 0980 PT J 0981 AU DAVIS, DD 0982 KILDUFF, JE 0983 KOONTZ, SL 0984 TI DIFFUSE REFLECTANCE INFRARED FOURIER-TRANSFORM (DRIFT) SPECTROSCOPIC 0985 STUDY OF ADSORBED HYDRAZINES 0986 SO SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY 0987 LA English 0988 DT Article 0989 AB Diffuse reflectance spectroscopy of fuel hydrazines adsorbed on silica, 0990 silica-alumina, alumina and ferric oxide surfaces indicates that the 0991 primary surface-hydrazine interaction is hydrogen bonding. Hydrazine, 0992 on adsorption to a deuterated silica surface, undergoes a rapid H/D 0993 exchange with deuterated surface silanol (Si-OD) groups. Adsorption 0994 equilibria are rapidly established at room temperature. 0995 Monomethylhydrazine and 1,1-dimethylhydrazine are similarly adsorbed. 0996 On adsorption, the C-H stretching and methyl deformation modes of the 0997 methylhydrazines are shifted to higher frequencies by 10-20 cm-1. 0998 These shifts are postulated to be due to changes in the lone-pair 0999 electron-density on the adjacent nitrogen-atom. From a linear 1000 relationship of the electronegativities and deformation frequencies it 1001 is estimated that adsorption results in a 5% increase in 1002 electronegativity of the H-bonded atom. 1003 C1 NASA,LOCKHEED EMSCO,JOHNSON SPACE CTR,WHITE SANDS TEST FACIL,LAS CRUCES,NM 88004. 1004 RP DAVIS, DD, NEW MEXICO STATE UNIV,DEPT CHEM,LAS CRUCES,NM 88003. 1005 NR 21 1006 TC 2 1007 PU PERGAMON-ELSEVIER SCIENCE LTD 1008 PI OXFORD 1009 PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD, ENGLAND OX5 1GB 1010 SN 0584-8539 1011 J9 SPECTROCHIM ACTA PT A-MOL BIO 1012 JI Spectroc. Acta Pt. A-Molec. Biomolec. Spectr. 1013 PY 1991 1014 VL 47 1015 IS 2 1016 BP 299 1017 EP 308 1018 PG 10 1019 SC Spectroscopy 1020 GA EZ868 1021 UT ISI:A1991EZ86800016 1022 ER 1023 1024 1025 PT J 1026 AU WEDLICH, RC 1027 DAVIS, DD 1028 TI NONISOTHERMAL KINETICS OF HYDRAZINE DECOMPOSITION 1029 SO THERMOCHIMICA ACTA 1030 LA English 1031 DT Article 1032 C1 NEW MEXICO STATE UNIV,DEPT CHEM,LAS CRUCES,NM 88003. 1033 NASA,LOCKHEED ENGN & SCI CO,WHITE SANDS TEST FACIL,LAS CRUCES,NM 88004. 1034 NR 25 1035 TC 5 1036 PU ELSEVIER SCIENCE BV 1037 PI AMSTERDAM 1038 PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS 1039 SN 0040-6031 1040 J9 THERMOCHIM ACTA 1041 JI Thermochim. Acta 1042 PD NOV 24 1043 PY 1990 1044 VL 171 1045 BP 1 1046 EP 13 1047 PG 13 1048 SC Chemistry, Analytical; Chemistry, Physical 1049 GA EK644 1050 UT ISI:A1990EK64400001 1051 ER 1052 1053 1054 PT J 1055 AU STONE, DA 1056 WISEMAN, FL 1057 KILDUFF, JE 1058 KOONTZ, SL 1059 DAVIS, DD 1060 TI THE DISAPPEARANCE OF FUEL HYDRAZINE VAPORS IN FLUOROCARBON FILM 1061 ENVIRONMENTAL CHAMBERS - EXPERIMENTAL-OBSERVATIONS AND KINETIC MODELING 1062 SO ENVIRONMENTAL SCIENCE & TECHNOLOGY 1063 LA English 1064 DT Article 1065 C1 NASA,WHITE SANDS TEST FACIL,LAS CRUCES,NM 88004. 1066 NEW MEXICO STATE UNIV,DEPT CHEM,LAS CRUCES,NM 88003. 1067 USAF,CTR ENGN & SERV,DIV ENVIRON,ENGN & SERV LAB,TYNDALL AFB,FL 32403. 1068 NR 15 1069 TC 5 1070 PU AMER CHEMICAL SOC 1071 PI WASHINGTON 1072 PA 1155 16TH ST, NW, WASHINGTON, DC 20036 1073 SN 0013-936X 1074 J9 ENVIRON SCI TECHNOL 1075 JI Environ. Sci. Technol. 1076 PD MAR 1077 PY 1989 1078 VL 23 1079 IS 3 1080 BP 328 1081 EP 333 1082 PG 6 1083 SC Engineering, Environmental; Environmental Sciences 1084 GA T4691 1085 UT ISI:A1989T469100014 1086 ER 1087 1088 1089 PT J 1090 AU DAVIS, DD 1091 WEDLICH, RC 1092 BENZ, FJ 1093 TI NON-ISOTHERMAL KINETIC-STUDIES OF HYDRAZINE DECOMPOSITION 1094 SO ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY 1095 LA English 1096 DT Meeting Abstract 1097 C1 NEW MEXICO STATE UNIV,DEPT CHEM,LAS CRUCES,NM 88003. 1098 NASA,JOHNSON SPACE CTR,WHITE SANDS TEST FACIL,LAS CRUCES,NM 88003. 1099 NR 0 1100 TC 0 1101 PU AMER CHEMICAL SOC 1102 PI WASHINGTON 1103 PA 1155 16TH ST, NW, WASHINGTON, DC 20036 1104 SN 0065-7727 1105 J9 ABSTR PAP AMER CHEM SOC 1106 JI Abstr. Pap. Am. Chem. Soc. 1107 PD JUN 5 1108 PY 1988 1109 VL 195 1110 PN Part 2 1111 BP 221 1112 EP PHYS 1113 PG 0 1114 SC Chemistry, Multidisciplinary 1115 GA P9362 1116 UT ISI:A1988P936201186 1117 ER 1118 1119 1120 PT J 1121 AU AKKERMAN, JW 1122 TI HYDRAZINE MONOPROPELLANT RECIPROCATING-ENGINE DEVELOPMENT 1123 SO JOURNAL OF ENGINEERING FOR INDUSTRY-TRANSACTIONS OF THE ASME 1124 LA English 1125 DT Article 1126 RP AKKERMAN, JW, NASA,LYNDON B JOHNSON SPACE CTR,HOUSTON,TX 77058. 1127 NR 0 1128 TC 0 1129 PU ASME-AMER SOC MECHANICAL ENG 1130 PI NEW YORK 1131 PA 345 E 47TH ST, NEW YORK, NY 10017 1132 SN 0022-0817 1133 J9 J ENG IND 1134 JI J. Eng. Ind.-Trans. ASME 1135 PY 1979 1136 VL 101 1137 IS 4 1138 BP 456 1139 EP 462 1140 PG 7 1141 SC Engineering, Mechanical 1142 GA HX846 1143 UT ISI:A1979HX84600011 1144 ER 1145 1146 1147 PT J 1148 AU STIEF, LJ 1149 PAYNE, WA 1150 TI ABSOLUTE RATE PARAMETERS FOR REACTION OF ATOMIC-HYDROGEN WITH HYDRAZINE 1151 SO JOURNAL OF CHEMICAL PHYSICS 1152 LA English 1153 DT Article 1154 C1 NASA GODDARD SPACE FLIGHT CTR,EXTRATERR PHYS LAB,ASTROCHEM BRANCH,GREENBELT,MD 20771. 1155 NR 22 1156 TC 24 1157 PU AMER INST PHYSICS 1158 PI WOODBURY 1159 PA CIRCULATION FULFILLMENT DIV, 500 SUNNYSIDE BLVD, WOODBURY, NY 11797-2999 1160 SN 0021-9606 1161 J9 J CHEM PHYS 1162 JI J. Chem. Phys. 1163 PY 1976 1164 VL 64 1165 IS 12 1166 BP 4892 1167 EP 4896 1168 PG 5 1169 SC Physics, Atomic, Molecular & Chemical 1170 GA BW208 1171 UT ISI:A1976BW20800013 1172 ER 1173 1174 1175 EF